Seawater density
Contents
Introduction
Density gradients play a prominent role in marine hydrodynamics. The largescale longterm mean currents in the ocean and in estuaries largely depend on the density differences between water masses. The same holds for the smallscale turbulent velocity fluctuations that are responsible for mixing processes in oceans, shelf seas and estuaries. Knowledge of the seawater density is therefore prerequisite for understanding and modelling marine processes.
The seawater density [math]\rho[/math] in the ocean mainly depends on salinity [math]S[/math], temperature [math]T[/math] and pressure [math]p[/math]. Pressure only plays a role at depths much greater than those of coastal waters. Because of the primary focus of the Coastal Wiki on coastal waters, the dependency on pressure will be ignored in this article.
Salinitytemperature dependence of seawater density
An accurate empirical expression for the densitysalinitytemperature relationship for coastal waters has been derived by Fonofoff and Millard (1983^{[1]}). This expression holds for the temperature range [math] 0\lt T\lt 40 \;[/math] ^{o}C, the salinity range [math] 0 \le S\lt 42 [/math] and for pressures lower than [math]p\lt 10[/math] bar. [math]S[/math] is the practical salinity.
[math]\rho = \rho_0 + (0.82454.1\, 10^{3} \,T+7.64\, 10^{5} \,T^28.25\, 10^{7} \,T^3+5.4\, 10^{9} \,T^4)\times S \\ +(5.7\, 10^{3} \,+10^{4} \,T1.65\, 10^{6} \,T^2)\times S^{3/2} + 4.8\, 10^{4}\,S^2 , \qquad (1)[/math]
[math]\rho_0 =999.84+6.8 \, 10^{2} \, T  9.1\, 10^{3} \, T^2+10^{4} \, T^31.1 \, 10^{6} \, T^4+6.5\, 10^{9} \, T^5 . \qquad (2)[/math]
The densitysalinitytemperature relationship is plotted in Fig. 1. More precise relationships have been established since; these relationships also include pressure effects^{[2]}^{[3]}. However, for coastal waters the increased accuracy is usually not required.
A simpler approximation of equations (1,2) with accuracy better than 1 ‰ is
[math]\rho = 999.1+ 0.77 \, (S\Large\frac{T15}{5.13}\frac{(T15)^2}{128}\normalsize) . \qquad (3)[/math]
In turbid coastal waters, the suspended sediment concentration in g / kg has to be added in this expression.
Processes induced by density differences
Seawater density decreases with increasing temperature and increases with increasing salinity. According to Eq. (3), an increase of 1 g / kg in salinity has about the same effect on the seawater density as a decrease of 45 ^{o}C in temperature. Warm, low salinity water tends to stay near the surface whereas cool, high salinity water tends to stay near the bottom. Evaporation of a warm surface layer increases its salinity, in which case it may sink; this occurs in the North Atlantic. Partial freezing of a low salinity surface layer may also induce sinking by increasing the salinity of the unfrozen water; this occurs in the polar regions. In both examples sinking is enhanced by cooling. Sinking of surface layers implies that subsurface layers of lower density will emerge; this process is called 'overturning'. The balance between small changes in salinity and temperature has great importance for the largescale ocean circulation.
In estuaries, the density effect of salinity gradients is generally much greater than the density effect of the temperature gradients, producing vertical salinity stratification and the wellknown estuarine circulation, which is driven by the density gradient along the estuarine axis, see Fig. 2. In contrast, in oceans, the density effect of temperature generally dominates the effect of salinity. In many parts of the oceans, both temperature and salinity decrease with depth.
Stratification
A body of water is referred to as 'stable' when the density decreases from bottom to surface. This is the usual situation, also in cases where strong mixing occurs over the water column. Mixing is mainly caused by turbulence, which is generated by frictional shear stresses at the bottom and the water surface. When the production of turbulent energy in an estuary decreases, inflowing river water and seawater will be less mixed: vertical density differences force the water column into a more stratified state, with the vertical density difference concentrated around a transition layer, the socalled pycnocline, see Fig. 3. This is a nonlinear process as a result of the hydrostatic pressure differences (buoyancy principle of Archimedes) that dampen turbulent fluid fluctuations around the pycnocline; the turbulent energy production needed for mixing increases as the stratification increases.
The suppression of mixing in stratified water bodies between the surface layer and the water layer below the pycnocline can have serious consequences for the aeration of the lower layer, because this is where the most mineralization takes place and thus the oxygen demand is greatest. Especially when the water is eutrophic (high organic content) and turbid, the oxygen demand in the lower layer leads to hypoxia, resulting in severe mortality of benthic organisms in particular (see also the article Estuarine turbidity maximum).
Water and salt cannot spontaneously unmix from an existing solution (this would be contrary to the second law of thermodynamics), but a suspension of fine sediment can unmix by settling. Settling of fine sediment in turbid coastal waters can increase the density in the lower part of the water column such that a pycnocline starts to develop. Damping of turbulence around the pycnocline furthers the settling process, which can eventually lead to the formation of a fluid mud layer (see the article Dynamics of mud transport).
Overturning
When denser (salty, cold) water is advected over less dense water by winddriven or tidedriven currents, the water column becomes unstable. The denser surface water will sink trough the underlying less dense water layer. This process is called convective overturning and contributes to the mixing of water masses of different density. It can occur, for example, when seawater enters a partially mixed estuary and a strong nearsurface flood current carries dense saline water over the underlying, less saline estuarine water^{[4]} (see also Estuarine circulation).
Overturning processes can also occur when surface water is heated by the sun and salinity is increased by evaporation. The density of the warm salty surface water may then exceed the density of the underlying layer of cooler water, in which case the warm salty surface water will sink through this cooler layer. The downward motion is accelerated, because the salty surface water is cooled while sinking. This leads to the formation of socalled 'salt fingers'^{[5]}, see Fig. 4. This overturning motion is not only important for the large scale ocean circulation, but it also causes upwelling of nutrientrich water from the bottom layer and thus stimulates primary production on which the ocean food web depends.
Related articles
 Salinity
 Ocean circulation
 Thermohaline circulation of the oceans
 Estuarine circulation
 Salt wedge estuaries
References
 ↑ Fofonoff, N.P. and Millard, R.C. 1983. Algorithms for computation of fundamental properties of seawater. Unesco technical papers in marine science 44
 ↑ IOC, SCOR and IAPSO 2010. The international thermodynamic equation of seawater – 2010: Calculation and use of thermodynamic properties. Intergovernmental Oceanographic Commission, Manuals and Guides No. 56, UNESCO, 196 pp
 ↑ Schmidt, H., Seitz, S., Hassel, E and Wolf, H. 2018. The density–salinity relation of standard seawater. Ocean Sci.: 14, 15–40
 ↑ Prandle, D. 2004. Saline intrusion in partially mixed estuaries. Estuarine Coastal and Shelf Science 59(3): 385397
 ↑ Kunze, E. 2003. A review of oceanic saltfingering theory. Progress In Oceanography 56: 399417
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